Thermodynamics of Mixtures Containing a Very Strongly Polar Compound. 10. Liquid–Liquid Equilibria for N,N-Dimethylacetamide + Selected Alkanes

Local Compositions and Thermodynamics of Polar/non-polar Mixtures

Results of computer simulations are presented for the thermodynamic properties of mixing and the local compositions for mixtures of Stockmayer and Lennard-Jones fluids with varying concentrations and dipole strengths The results show a strong asymmetry with respect to the concentration which is attributed to the influence of the orientation dependence of the dipoledipole interaction and explain...

Predicting the High-Pressure Phase Equilibria of Binary Mixtures of Perfluoro-n-alkanes + n-Alkanes Using the SAFT-VR Approach

The phase behavior of perfluoro-(n)-alkane + (n)-alkane binary mixtures is of particular interest given their unexpected large positive deviations from Raoult’s law. Binary mixtures of perfluoromethane + (n)-alkanes from methane to heptane are studied here, illustrating the continuous change in phase behavior from type II to type III that these systems exhibit. Some symmetrical systems that dis...

Isobaric Vapor Liquid Equilibria of Systems containing N-Alkanes and Alkoxyethanols

Liquid Density of Alkanes and Halogenated Alkanes Mixtures in a Corresponding States Format

The Corresponding States (CS) density models for mixture proposed here, one for saturated and one for compressed liquid, are analytically similar to the pure fluid liquid density exposed in the former paper, but now with critical constants and 8,, replacing wm , as from the mixing rules. The mixing rules present two adjustable interaction coefficients for each binary pair, but they are set to u...

Recent developments in thermodynamics and thermophysics of non-aqueous mixtures containing ionic liquids. A review

Mixtures of ionic liquids with organic solvents exhibit a most interesting research area in thermodynamics. The increasing utilization of ionic liquids in chemical processes and separation processes requires reliable and systematic data of thermodynamic and thermophysical properties such as activity coefficients, VLE and LLE data, heats of mixing as well as gas solubility data, densities and tr...